New Organic p-Conjugated Systems Derived
From Pentacene-5,7,12,14-tetraone
Dr. Eyad Younes
Assistant Professor
Department of Chemistry
The Hashemite University
Zarqa-Jordan
د.اياد يونس
استاذ مساعد
قسم الكيمياء
الجامعة الهاشمية
الزرقاء-الاردن
Place: Seminar Room, Department of Chemistry المكان : قاعة النشاطات / قسم الكيمياء
Date & Time: Wednesday 06/3/2019 at 12:30 pm 2019 الساعة 12:30 ظهرا /03/ الزمان: الاربعاء 06
ABSTRACT
Pentacene and its derivatives have unique optoelectronic properties, which make them promising
materials in molecular electronic devices such as organic light-emitting diodes (OLEDs)1 and
organic field-effect transistors (OFETs)2. In this presentation, we report our recent studies on the
functionalization of pentacene-5,7,12,14-teraone by olefination and transition-metal catalyzed
cross-coupling reactions. A new class of pi-conjugated donor/acceptor systems has been
synthesized using pentacenetetraone as the precursor, while the structural, electronic and redox
properties of these compounds were characterized by spectroscopic analyses in conjunction with
density functional theory (DFT) calculations.3-4
(1) Kitamura, M.; Imada, T.; Arakawa, Y. Appl. Phys. Lett. 2003, 83 (16), 3410.
(2) Horowitz, G. Adv. Mater. 1998, 10 (5), 365-377.
(3) Younes, E. A.; Zhao, Y. RSC Adv. 2015, 5 (108), 88821.
(4) Younes, E. A.; Zhao, Y. Org. Chem. Front., 2017, 4, 804-810